Luminescence characteristics of Eu2+ activated Ca2SiO4, Sr2SiO4 and Ba2SiO4 phosphors for white LEDs
- Available Online: 30/05/2009
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Key words:
- luminescence /
- white LEDs /
- Eu2+ /
- silicate
Abstract: This paper investigates the luminescence characteristics of Eu2+ activated Ca2SiO4, Sr2SiO4 and Ba2SiO4 phos-phors. Two emission bands are assigned to the f-d transitions of Eu2+ ions doped into two different cation sites in host lattices, and show different emission colour variation caused by substituting M2+ cations for smaller cations. This be-haviour is discussed in terms of two competing factors of the crystal field strength and covalence. These phosphors with maximum excitation of around 370 nm can be applied as a colour-tunable phosphor for light-emitting diodes (LEDs) based on ultraviolet chip/phosphor technology.