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2007 Volume 16 Issue 10
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Liu Li, Niu Ying-Yu, Yuan Kai-Jun, Cong Shu-Lin. 2007: Control of photoassociation reaction F+H→HF with ultrashort laser pulse, Chinese Physics B, 16(10): 2957-2961.
Citation: Liu Li, Niu Ying-Yu, Yuan Kai-Jun, Cong Shu-Lin. 2007: Control of photoassociation reaction F+H→HF with ultrashort laser pulse, Chinese Physics B, 16(10): 2957-2961.
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Control of photoassociation reaction F+H→HF with ultrashort laser pulse

  • Department of Physics, Dalian University of Technology, Dalian 116024, China

  • Available Online: 30/10/2007
  • Fund Project: the National Natural Science Foundation of China (Grant 10674022 and 20633070)
  • The laser-induced vibrational state-selectivity of product HF in photoassociation reaction H+F→HF is theoretically investigated by using the time-dependent quantum wave packet method. The population transfer process from the continuum state down to the bound vibrational states can be controlled by the driving laser. The effects of laser pulse parameters and the initial momentum of the two collision atoms on the vibrational population of the product HF are discussed in detail. Photodissociation accompanied with the photoassociation process is also described.
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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Control of photoassociation reaction F+H→HF with ultrashort laser pulse

  • Available Online: 30/10/2007

Abstract: The laser-induced vibrational state-selectivity of product HF in photoassociation reaction H+F→HF is theoretically investigated by using the time-dependent quantum wave packet method. The population transfer process from the continuum state down to the bound vibrational states can be controlled by the driving laser. The effects of laser pulse parameters and the initial momentum of the two collision atoms on the vibrational population of the product HF are discussed in detail. Photodissociation accompanied with the photoassociation process is also described.

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